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List the types of physical changes that can yield exothermic and endothermic peaks in DTA and DSC.

In DTA and DSC, various physical changes can yield exothermic and endothermic peaks. Some examples of physical changes that can cause these peaks are:

Exothermic Peaks:

  • Crystallization or recrystallization
  • Solid-solid phase transitions (e.g., polymorphic transitions)
  • Combustion or oxidation reactions
  • Decomposition of organic compounds
  • Adsorption or desorption of gases

Endothermic Peaks:

  • Melting or solidification
  • Glass transition
  • Vaporization or sublimation
  • Absorption of moisture or other solvents by a sample

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